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1. Thermopile detectors
2. Bolometers
Thermal detectors CHAPTER 07 1 Thermopile detectors 1-1 Features 1-2 Structure 1-3 Characteristics 1-4 How to use 1-5 New approaches 1-6 Applications 2 Bolometers 2-1 Operating principle and structure 2-2 Characteristics 1
Thermal detectors Thermal detectors have an absorption layer that absorbs and converts light into heat, and provide an electric signal output that represents the change in absorption layer temperature. Because thermal detectors have no wavelength dependence, they can serve as infrared detectors when used with a window material such as Si that transmits infrared light. Thermal detectors are mainly classified into: (1) thermopile detectors that change in electromotive force, (2) bolometers that change in resistance, (3) pyroelectric detectors that change in dielectric surface charge, and (4) diodes that change in voltage- current characteristics. Hamamatsu manufactures two types of thermal detectors: thermopile detectors and bolometers. These two types of thermal detectors are different in terms of operating principle, structure, and characteristics. Thermopile detectors have a structure in which a large number of thermocouples are serially connected on a silicon substrate and their sensitivity increases as more thermocouples are used. This means that the larger the photosensitive area, the higher the sensitivity, because the number of thermocouples is proportional to the size of the photosensitive area. In bolometers, the photosensitive area uses a bolometer resistance made up of thermoelectric conversion materials, so the resistance temperature coefficient is the primary cause in determining bolometer sensitivity. Since bolometer sensitivity does not depend on the size of the photosensitive area, detectors can be fabricated that have a small photosensitive area yet no drop in sensitivity. Thermopile detectors are usually manufactured as single-element detectors with an ample photosensitive area or arrays with a small number of elements, while bolometers are manufactured as arrays with a larger number of elements than thermopile detectors. Hamamatsu thermopile detectors and bolometers Product name Multi-element array Sensitivity enhancement Supply current Package atmosphere Rise time Thermopile detector Possible with larger pixel size (pixel size: 200 × 200 µm or larger) Possible Not required (thermal electromotive force) Nitrogen 1 ms or more Bolometer Possible with smaller pixel size (pixel size: 75 × 75 µm or smaller) Possible Required Vacuum 2 ms or more 2
1. Thermopile detectors [Figure 1-1] Thermally isolated structure (thermopile detector) Thermocouple Hot junction Metal A Metal B T Δ ΔV Cold junction Hot junction T Δ Cold junction n × ΔV Our thermopile detector structures differ according to the type of device, namely, single/dual/quad element types and linear/area arrays. KIRDC0046EA Single/dual/quad element types Single/dual/quad element types have large photosensitive areas and are manufactured by bulk processing technology with high workability. Etching is performed from the backside of the substrate to form the photosensitive area in a membrane state so that the hot and cold junctions are thermally isolated from each other to achieve high sensitivity. [Figure 1-2] Cross-sectional view (single/dual/quad element types) Cold junction Photosensitive area Infrared absorption film Hot junction Thermocouple Isolation layer Substrate KIRDC0106EA Thermopile detectors are thermal detectors that utilize the Seebeck effect in which a thermal electromotive force is generated in proportion to the incident infrared light energy. Thermopile detectors themselves have no wavelength dependence and so are used with various types of window materials for diverse applications such as temperature measurement, human body sensing, and gas analysis. 1 - 1 Features Operates at room temperature Spectral response characteristics that are not dependent on wavelength No optical chopping is required, and voltage output can be obtained according to input energy. Low cost Long life 1 - 2 Structure In order to obtain a large output voltage, Hamamatsu thermopile detectors have many thermocouples that are serially connected on a silicon substrate to magnify the temperature difference between the hot and cold junctions. The hot junction side (photosensitive area) is designed to be a thermally isolated structure on which an infrared absorption film is attached. To make the thermally isolated structure, MEMS technology is used to process the membrane (thin film) to make it float in a hollow space. Our thermopile detectors use materials that have a large Seebeck coefficient (thermal electromotive force) and are easily formed by the semiconductor process. When infrared light enters a thermopile detector having the above mentioned structure, the hot junction on the membrane heats up and produces a temperature difference (ΔT) between the hot and cold junctions accompanied by generation of a thermal electromotive force (ΔV). [Table 1-1] Hamamatsu thermopile detectors Type Number of elements Window material Spectral response range Package Main applications Single element Dual element Quad element Linear array Area array 1 2 4 16, 32 8 × 8 Anti-reflection coated Si 3 to 5 µm TO-18 Gas analysis, temperature measurement Band-pass filter 3.9 µm, 4.3 µm 3 to 5 µm TO-5 TO-8 Gas analysis 5 µm long-pass filter 5 to 14 µm Flat package Temperature measurement TO-8 Temperature measurement, human body sensing 3
Linear and area arrays Temperature characteristics [Figure 1-4] Temperature characteristics of sensitivity (single element type T11262-01, typical example) 60 ) W / V ( y t i v i t i s n e S 58 56 54 52 50 48 46 44 42 40 -20 -10 0 10 20 30 40 50 60 70 80 Element temperature (°C) KIRDB0522EA [Figure 1-5] Temperature characteristics of element resistance (T11262-01, typical example) 150 140 130 120 110 ) Ω k ( e c n a t s i s e r t n e m e E l 100 -20 -10 0 10 20 30 40 50 60 70 80 Element temperature (°C) KIRDB0523EA Linearity Figure 1-6 shows an example of the relation between the input energy and output voltage. Thermopile detector output voltage is proportional to the input energy. To manufacture linear and area arrays, the gap between each element must be made narrow in order to reduce non-sensitive areas. To do this, the portion directly under each photosensitive area is selectively bored by surface processing technology so that the photosensitive area becomes a thin membrane-like structure. CMOS process technology is utilized to lay out the signal processing circuits on the same chip where the thermopile section is formed. [Figure 1-3] Cross-sectional view (linear and area arrays) Thermocouple Cold junction Hot junction Infrared absorption film Isolation layer Etching hole Metal wiring Substrate Thermopile section Thermopile section Signal processing circuit KIRDC0107EA 1 - 3 Characteristics Sensitivity Thermopile sensitivity (Rv) is determined by the number of thermocouples as expressed by equation (1). η n α Rv = [V/W] ……… (1) G 1 + ω2τ2 η : emissivity n : number of thermocouples α : Seebeck coefficient G : thermal conductivity ω : angular frequency τ : thermal time constant Noise Thermal noise called Johnson noise in the element resistance is predominant in thermopile detector noise. Noise (VN) is expressed by equation (2). VN = 4k T Rd Δf [V rms] ……… (2) k : Boltzmann’s constant T : absolute temperature Rd : element resistance Δf : bandwidth 4
[Figure 1-6] Output voltage vs. input energy (T11262-01, typical example) (Ta=25 ˚C) 10-1 10-2 10-3 10-4 10-5 ) V ( e g a t l o v t u p t u O 10-6 10-5 10-4 10-3 10-2 10-1 Input energy (W/cm2) KIRDB0560EA [Figure 1-7] Frequency characteristics ) B d ( t u p t u o e v l i t a e R 2 1 0 -1 -2 -3 -4 -5 0.1 (Typ. Ta=25 ˚C) 0.25 × 0.25 mm 0.3 × 0.3 mm 2 × 2 mm 1.2 × 1.2 mm 1 10 100 1000 Frequency (Hz) KIRDB0561EA Frequency characteristics Spectral response Figure 1-7 shows the frequency characteristics of thermopile detectors each having a different photosensitive area. Frequency response tends to decrease as the photosensitive area becomes larger. Since thermopile detectors have no wavelength dependence, their spectral response is determined by the transmittance characteristics of window materials. Spectral transmittance characteristics of typical window materials are shown in Figure 1-8. 1 - 4 How to use Single/dual/quad element types (1) Circuit not using thermistor In cases where the ambient temperature is constant or high precision measurement is not required, thermopile detectors can be used with a circuit that does not include a thermistor. [Figure 1-8] Spectral transmittance characteristics of window materials ) % ( e c n a t t i m s n a r T 100 90 80 70 60 50 40 30 20 10 0 2.5 Anti-reflection coated Si T11262-01 5 μm long-pass filter 8 to 14 μm band-pass filter 3.9 μm band-pass filter T11722-01 (reference light) Si 4.3 μm band-pass filter T11722-01 (CO2) 4.4 μm band-pass filter 5 7.5 10 12.5 15 17.5 20 22.5 25 Wavelength (μm) KIRDB0512EA 5
Dual-polarity power supply type [Figure 1-9] Amplifier circuit (dual-polarity power supply type) method using a microcontroller is more common. Figure 1-11 shows a circuit example where the thermistor output signal is fed into the amplifier circuit. This type of circuit is used when high measurement accuracy is not required. The circuit shown in Figure 1-11 applies to both cases where the thermistor is externally connected to the thermopile detector or the thermistor is built into the thermopile detector. [Figure 1-11] Amplifier circuit with thermistor Vout +V Thermopile detector Thermistor Rth Rd Ra Rb Rc 6 Vout +V 3 2 7 + - 4 -V R2 C1 R1 Gain = 1 + (R2/R1) fhigh = 1/(2πR2 C1) Vth KIRDC0051EB Finding the resistance values (Ra, Rb, Rc, Rd) for the circuit with a thermistor To find the resistance value of Rd at which the thermistor output Vth is linear in the operating temperature range 1) Determine the operating temperature range (Tmin to Tmax). 2) Find the resistance value (Rh) of the thermistor Rth at Tmax. 3) Find the resistance value (Rl) of the thermistor Rth at Tmin. 4) Find the resistance value (Rm) of the thermistor Rth at an intermediate temperature between Tmin and Tmax. 5) Find the resistance value of Rd from equation (3). Rh Rm + Rl Rm - 2Rh Rl Rd = ……… (3) Rh + Rl - 2Rm To measure the thermopile output voltage Vout and check the voltage range where the thermistor output voltage (Vth) varies in the operating temperature range (when the measurement object's temperature is 25 °C) 1) Measure the thermopile detector output voltage (Voutmin) at Tmax. 2) Measure the thermopile detector output voltage (Voutmax) at Tmin. C1 R2 6 -V 2 3 - + 4 7 +V R1 Thermopile detector Gain = 1 + (R2/R1) fhigh = 1/(2πC1 R2) KIRDC0049EA Single power supply type When using an op amp that operates from a single power supply, an error occurs near ground potential which is caused by the op amp’s offset voltage and nonlinearity. To cope with this, the thermopile detector is operated with one terminal biased. In the circuit shown in Figure 1-10, the op amp supply voltage is biased with dividing resistors R3 and R4. [Figure 1-10] Amplifier circuit (single power supply type) C1 R2 GND 4 7 2 3 - + +V R1 Thermopile detector 6 Vout Gain = 1 + (R2/R1) fhigh = 1/(2πC1 R2) +V R3 R4 KIRDC0050EB To find the resistance values of Ra, Rb and Rc (2) Circuit using thermistor Output signals of a thermopile detector are temperature dependent. When detecting the temperature of an object in locations where the thermopile element temperature may drastically fluctuate, some means of making the output signals constant is required to ensure stable temperature detection. There are two methods to compensate for the temperature: one is to directly input the thermopile detector and thermistor signals into a microcontroller, and the other is to feed the thermistor output signal into the amplifier circuit. If high accuracy is necessary, the 6 1) Find the voltage drop (Vb) of Rb and the voltage drop (Vc) of Rc, from the simultaneous equations (4) and (5). Voutmin = + Vc ……… (4) Vb Rd Rh + Rd Voutmax = + Vc ……… (5) Vb Rd Rl + Rd
2) Find the voltage drop (Va) of Ra. (b) T11264 series Va = V - Vb - Vc ……… (6) V: supply voltage 3) Determine the Rb value which should be smaller than Rth + Rd by at least two orders of magnitude. Temperature sensor (+) Vdd Vref Az_in Naz_hold_in Naz_on 4) Find the Ra and Rc values from the simultaneous Video LPF Temperature sensor COM Vdd GND Thermopile detector r e t s i g e r t f i h s l a c i t r e V Vsp Vclk Reset equations (7) and (8). Preamplifier Horizontal shift register Va = ……… (7) V Ra Ra + Rb + Rc V Rc Vc = ……… (8) Ra + Rb + Rc Linear and area arrays Linear and area arrays consist of a one- or two-dimensional thermopile array, shift registers and temperature sensor, and to which a preamplifier is hybrid-connected to amplify the output signal. Since the preamplifier is built into the same package, this reduces external noise and also simplifies the circuit configuration connected subsequent to the sensor. [Figure 1-12] Block diagram (a) T11263 series Temperature sensor Thermopile detector Temperature sensor (+) Address switch LPF Video Shift register Preamplifier Hsp Hclk KIRDC0113EA (1) Driving method The voltage to linear and area arrays is supplied from a 5 V single power supply. The timing pulse to each terminal is input as shown in the timing chart below so that the signal (Video signal) from each element of the thermopile array is output in a time series. [Figure 1-13] Timing chart (T11264 series) Vsp Vclk Hsp Hclk Reset Az_in Naz_hold_in Naz_on Vsp Vclk Hsp Hclk Reset Az_in Naz_hold_in Naz_on AD_trig Video 1 2 3 4 5 6 7 8 1 2 1 2 3 4 5 6 7 8 1 2 3 4 5 6 7 8 1 9 KIRDC0114EA d d V p D S N G l k C r o n h P i t e s e R f e r V i n _ z A i l n _ d o h _ z a N n o _ z a N (2) Temperature sensor KIRDC0112EA In linear and area arrays, a temperature sensor is mounted on the same chip where the thermopile is formed. When a constant current flows in this temperature sensor, a voltage signal can be obtained that is inversely proportional to the temperature. A Si diode is used in the temperature sensor, which typically has a temperature coefficient of approximately -2.2 mV/°C. [Table 1-2] Digital input description (linear and area arrays) Digital input Vsp, Hsp Vclk, Hclk Reset Video Az_in Description Input logic signals needed to start the vertical/horizontal shift register scans. These inputs are required to scan the shift registers. Input logic signals needed to switch the vertical/horizontal shift register channels. The shift register scan speed can be adjusted by changing the clock rate. Input logic signal for setting the video output to a fixed potential while the pixel output signals are not read out This outputs the thermopile detector signals in synchronization with the vertical/horizontal shift register scan timing. Naz_hold_in Logic signals for driving the internal amplifier Naz_on AD_trig Timing signal for acquiring the video signal into an external A/D converter, etc. This is used in synchronization with the logic signals to the input terminals. 7
[Figure 1-14] Temperature sensor forward current vs. temperature (T11264 series, typical example) ) V ( e g a t l o v d r a w r o F 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 0 (If=10 μA) 20 40 60 80 Temperature (°C) KIRDB0563EA 1 - 5 New approaches We are further enhancing our in-house CMOS and MEMS technologies to develop thermopile detectors with higher performance and more sophisticated functions yet at a lower cost. We also plan to offer small thermopile detectors with a lens, which come in a wafer level package. 1 - 6 Applications CO2 sensors Thermopile detectors are used for non-dispersive infrared (NDIR) detection type CO2 sensors. These CO2 sensors allow precision measurements with high accuracy (minimal error deviation from the true value). Temperature and human body sensing in specific areas Thermopile linear and area arrays are used for temperature and human body sensing in specific areas such as for air conditioner operation control. These can detect locations where persons are present and the direction that a person moves. 2. Bolometers Bolometers are small infrared sensors that do not require cooling. When infrared light enters a bolometer, the bolometer resistance heats up, causing a change in its resistance. This change is converted into a voltage for readout. Bolometers include a readout circuit to minimize intrusion of external noise. 2 - 1 Operating principle and structure Since bolometers are thermal detectors, the membrane (thin film) that absorbs infrared light must be thermally isolated from the substrate, so the structure has two long, thin legs called “beams” to support the membrane. The membrane is formed by sacrificial layer etching and floats about 2 µm from the substrate. Infrared light radiated from an object is absorbed by the infrared absorber on the membrane, causing the membrane temperature to increase and the bolometer resistance to decrease. The incident light level can be read out as a voltage signal by applying an electric current to the bolometer resistance. As the bolometer resistance material, we use a-Si (amorphous silicon) whose resistance greatly varies with temperature. A CMOS readout circuit (ROIC: readout integrated circuit) is fabricated on the substrate. [Figure 2-1] Cross-sectional view (one pixel) Bolometer resistance Infrared absorber Infrared light Substrate (CMOS readout circuit) Beam Isolation film a-silicon Electrode KIRDC0115EA [Figure 2-2] Enlarged photograph of photosensitive area (bolometer) 8
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