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Contents
List of symbols
1 Introduction
2 Overview of macroscopic thermal sciences
3 Elements of statistical thermodynamics and quantum theory
4 Kinetic theory and micro/nanofluidics
5 Thermal properties of solics and the size effect
6 Electron and phonon transport
7 nonequilibrium energy transfer in nanostructures
8 Fundamentals of thermal radiation
8.4.3 The Lorentz Oscillator
9 Radiative properties of nanomaterials
10 Near-field energy transfer
Appendix A
Appendix B
NANO/MICROSCALE HEAT TRANSFER
ABOUT THE AUTHOR Zhuomin M. Zhang has taught at the University of Florida (1995–2002) and the Georgia Institute of Technology (since 2002). Professor Zhang is an ASME Fellow and has done cutting-edge research in the areas of micro/nanoscale heat transfer, with applications to optoelectronic devices and semiconductor manu- facturing. He is a recipient of the Presidential Early Career Award for Scientists and Engineers (PECASE), the ASME Heat Transfer Division Best Paper Award, and the AIAA Thermophysics Best Paper Award. Professor Zhang currently serves on the Editorial Board of the International Journal of Thermophysics and is an associate editor for the Journal of Quantitative Spectroscopy & Radiative Transfer and the Journal of Thermophysics and Heat Transfer. Copyright © 2007 by The McGraw-Hill Companies, Inc. Click here for terms of use.
NANO/MICROSCALE HEAT TRANSFER Zhuomin M. Zhang Georgia Institute of Technology Atlanta, Georgia New York Chicago San Francisco Lisbon London Madrid Mexico City Milan New Delhi San Juan Seoul Singapore Sydney Toronto
Copyright © 2007 by The McGraw-Hill Companies, Inc. All rights reserved. Manufactured in the United States of America. Except as permitted under the United States Copyright Act of 1976, no part of this publication may be reproduced or distributed in any form or by any means, or stored in a data- base or retrieval system, without the prior written permission of the publisher. 0-07-150973-9 The material in this eBook also appears in the print version of this title: 0-07-143674-X. All trademarks are trademarks of their respective owners. Rather than put a trademark symbol after every occurrence of a trademarked name, we use names in an editorial fashion only, and to the bene- fit of the trademark owner, with no intention of infringement of the trademark. Where such designa- tions appear in this book, they have been printed with initial caps. McGraw-Hill eBooks are available at special quantity discounts to use as premiums and sales promo- tions, or for use in corporate training programs. For more information, please contact George Hoare, Special Sales, at george_hoare@mcgraw-hill.com or (212) 904-4069. TERMS OF USE This is a copyrighted work and The McGraw-Hill Companies, Inc. (“McGraw-Hill”) and its licensors reserve all rights in and to the work. Use of this work is subject to these terms. Except as permitted under the Copyright Act of 1976 and the right to store and retrieve one copy of the work, you may not decompile, disassemble, reverse engineer, reproduce, modify, create derivative works based upon, transmit, distribute, disseminate, sell, publish or sublicense the work or any part of it without McGraw-Hill’s prior consent. You may use the work for your own noncommercial and personal use; any other use of the work is strictly prohibited. Your right to use the work may be terminated if you fail to comply with these terms. THE WORK IS PROVIDED “AS IS.” McGRAW-HILL AND ITS LICENSORS MAKE NO GUARANTEES OR WARRANTIES AS TO THE ACCURACY, ADEQUACY OR COMPLETE- NESS OF OR RESULTS TO BE OBTAINED FROM USING THE WORK, INCLUDING ANY INFORMATION THAT CAN BE ACCESSED THROUGH THE WORK VIA HYPERLINK OR OTHERWISE, AND EXPRESSLY DISCLAIM ANY WARRANTY, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. McGraw-Hill and its licensors do not warrant or guarantee that the functions contained in the work will meet your requirements or that its operation will be uninterrupted or error free. Neither McGraw-Hill nor its licensors shall be liable to you or anyone else for any inaccuracy, error or omission, regardless of cause, in the work or for any damages resulting therefrom. McGraw-Hill has no responsibility for the content of any information accessed through the work. Under no circumstances shall McGraw-Hill and/or its licensors be liable for any indirect, incidental, special, punitive, consequential or similar damages that result from the use of or inability to use the work, even if any of them has been advised of the possibility of such damages. This limitation of liability shall apply to any claim or cause whatsoever whether such claim or cause arises in contract, tort or otherwise. DOI: 10.1036/007143674X
To my wife Lingyun
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For more information about this title, click here CONTENTS Preface List of Symbols xiii xvii Chapter 1. Introduction 1 1.1 Limitations of the Macroscopic Formulation / 2 1.2 The Length Scales / 3 1.3 From Ancient Philosophy to Contemporary Technologies / 5 1.3.1 Microelectronics and Information Technology / 6 1.3.2 Lasers, Optoelectronics, and Nanophotonics / 8 1.3.3 Microfabrication and Nanofabrication / 10 1.3.4 Probing and Manipulation of Small Structures / 12 1.3.5 Energy Conversion Devices / 15 1.3.6 Biomolecule Imaging and Molecular Electronics / 17 1.4 Objectives and Organization of This Book / 19 References / 22 Chapter 2. Overview of Macroscopic Thermal Sciences 25 2.1 Fundamentals of Thermodynamics / 25 2.1.1 The First Law of Thermodynamics / 26 2.1.2 Thermodynamic Equilibrium and the Second Law / 27 2.1.3 The Third Law of Thermodynamics / 31 2.2 Thermodynamic Functions and Properties / 32 2.2.1 Thermodynamic Relations / 32 2.2.2 The Gibbs Phase Rule / 34 2.2.3 Specific Heats / 36 2.3 Ideal Gas and Ideal Incompressible Models / 38 2.3.1 The Ideal Gas / 38 2.3.2 Incompressible Solids and Liquids / 40 2.4 Heat Transfer Basics / 41 2.4.1 Conduction / 42 2.4.2 Convection / 44 2.4.3 Radiation / 46 2.5 Summary / 51 References / 51 Problems / 52 Chapter 3. Elements of Statistical Thermodynamics and Quantum Theory 57 3.1 Statistical Mechanics of Independent Particles / 58 3.1.1 Macrostates versus Microstates / 59 3.1.2 Phase Space / 59 vii
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